not sure there is so many uses for copper bolts nails screws washers and so many other copper parts. from compression washers for engines to bolts for things that may only need a moderate strength bolt something that is going to be hard to get to and not often so that way it holds up so much longer to the elements. as for history if this helps for these size bolts may be used for ships, if you visit boston you will hear the debate how how paul revere was hired to either make or reduce the size of copper bolts used in the building of the uss constitution
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