The spark test will help--SS sparks a little, brass not at all when touched to a grinding wheel.
Take a look at the ground surface, too. The brass will be yellowish, the SS shiny, steel-coloured. Also, a magnet may be faintly attracted to the SS...just faintly. This is hard to tell sometimes...I've seen the experts use a magnet dangled from a keychain so it is easier to tell if there is a faint attraction.
Jon.
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