I'm with AKman, respond with interest and say a few reassuring things. I say I am very interested in said item, I'm in your nieghborhood/city, here's my first name and cell. I can come in a few hours, tonight, or tomorrow as options, also flexible. If you respond to me, I answer the cell, and I always show up, unlike some CL flakes out there. I think you're ahead of the game if they already know when you can come. You are communicating in advance something they will have to ask you anyway.
If/when they respond, I confirm I'll show up, and will call if I can't.
As other free stuff easier to get, try Freecycle. I think it's in most areas. The one in my city, stresses the people giving away that they are not allowed to post free-for-all type ads, as it is inconsiderate and often someone really needing the free usuable itme(s) may not be able to afford gas for wild goose chases. They suggest people post the free items (s) wait for a few response emails from people interested and then choose one to email back and give out address.
For Freecycle I use the same type of response. I give them name/number and some feel-good info, In the neighborhood, etc.
You can also post wanted ads on freecycle. It's far more tame than CL. I quit responding for a while, as I got overloaded with stuff. Have to pair down before hauling home more, LOL.
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